Method of safe storage of waste

专利摘要:
The invention relates to the field of environmental protection, in particular to the storage of industrial waste. The purpose of the invention is to increase efficiency. To do this, spent catalyst based on iron oxide (waste of the petrochemical industry) or spent crushed gas cleaning mass (waste of coke plants) is mixed with brown coal ash (waste of power plants) and water in a ratio, wt. 5-50: 100: 20-40 to obtain a fluidized fluid mass and store it in a heap by distributing it along the bottom and side surfaces of the heap. 1 tab.
公开号:SU1547699A3
申请号:SU853944426
申请日:1985-08-22
公开日:1990-02-28
发明作者:Хайде Гюнтер；Вернер Ханс
申请人:Тифбау Хайнрих Бенер Гмбх (Фирма)；
IPC主号:

专利说明:

The invention relates to the protection of the environment, in particular, to a method for the safe storage of solid waste or emissions dissolved in an aquatic environment, using brown coal ash.
The purpose of the invention is to increase the efficiency of the process by disposing of additional solid toxic waste. uh
In the proposed method for storage, brown coal ash is used — waste of power plants as solid waste, spent catalyst based on iron oxide — waste of the petrochemical industry, or spent crushed gas cleaning mass — waste of coke plants, and water, at a ratio in wt / h, 100: : (5-50): (20-40).
Thus, when mixing two completely different and unsuitable
for storing waste and water, one solid product is obtained, which, due to its density and compactness, is waterproof and especially suitable for dumping.
Widespread technical use can be caused if the ash of brown coal, removed from power plants, is transported using transport devices, and solid waste separately.
i1
Both of these components in the required quantities should be measured in the mixer directly at the dumping site of the resulting inert compact product. Incoming, mixing and unloading can occur continuously. The mixing plant can be mounted directly on a strip otgoform.
ate
4b vl
About CO
 CM
Until now, usually emitted substances, when stored at the dump site, there is a risk of contamination of groundwater, were sealed either with pure clay or dumped into developed clay pits, on the base and walls of which there are still several meters of natural clay. Due to the shortage of clay and an insufficient number of open clay pits, artificial film is used as a bonding material. When implementing the proposed method, such steps are unnecessary.
The side walls and the bottom plane of the dump are effectively compacted to the level of the formation, which prevents the infiltration of harmful substances into the soil. Thus, virtually no adverse effects on groundwater are excluded. The water flowing to the bottom of the heap can be collected in 2 drains and drained without causing harm.
It is preferable to use the mixture for filling natural underground cavities or hollowed-out hollow spaces. In this case, it is advisable to add water in such an amount and at such a time to the mixture of ash of brown coal ejected from power plants and other wastes so that when the mixture is transported to the dump site, it is fluid. This method prevents the penetration of sulfates, chlorides and other harmful substances into the ground water. substances that are formed during the weathering of the rock. Rain water from the sealing layer made by the proposed method can be drained off by drains located on its surface and eliminated without any damage.
For the implementation of the method, both wet humid ash in the form of dust, which is collected from power plant bunkers, and wet, which after removal from power plants is located, for example, in open pit mines, where it has arrived for storage, is suitable.
The ash from power plants contains the mineral substance of pure coal and impurities of sand and clay associated with coal supplied at the site 3
five
,five
5, - g
Jq 5
, g 35
50
five
niy Most of this ash is a fine fraction from electrostatic precipitators, and a smaller part is coarse-dispersion boiler ash with a high sand content.
The chemical and physical properties of the brown coal ash coming from power plants are mainly determined by the calcium content. It is present in the ashes in the form of oxide, ferrite and calcium sulphate. The high reactivity is further enhanced by the fine grain size of the ash and its large inner surface.
Without deteriorating the sintering properties of the coal coal ash, up to 50 wt.% Solids can be mixed with it. Solid waste is most often found in powdered or granular form, sometimes in lumpy form, and it is advisable to dry them homogeneously with brown coal ash from power plants and then add the required amount of water.
After a short period of time, the porridge-like mixture, which is further compacted by applying mechanical effects (for example, shaking, rolling a track line or rollers on it), is cemented due to chemical transformations that occur during heating.
Example 1. Used solid waste based on iron oxide, which is a waste of the petrochemical industry, is used as solid waste. These spent catalysts have such a high content of a water soluble mouse that they can only be stored in special landfills. The catalyst used is a centimeter mold. Within 24 hours, this material is washed with distilled water at a ratio of 1:10 with its constant circulation, after which the filtrate has a drying ratio of 1.3 mg / l.
Death of May 30, h. spent catalyst, 100 mas. ashes of brown coal and 20-40 ma.ch. the water becomes a compact, dense, extremely rigid body, for which Kf, which determines the water permeability, is 910 m / s. After washing, the content of the mouse in the filtrate is below the limit.
0.03 mg / l and, therefore, below the acceptable value for drinking water 0.05 mg / l.
Example 2. A periodic Airm Dries, Mannheim blender with a non-moving mixing drum is used, in which mixing tools mounted on a horizontal shaft are working. Brown coal ash is accumulated in large silage tanks. For the experiment, 100 kg of brown coal ash is selected from the silo, weighed, and fed to the mixer. After that, a certain amount of solid waste (50-80 kg) is weighed and fed into the mixer, after which the mixing process begins. The mixing time is 30 seconds or more and water is added.
The results of the experiments are shown in the table.
If the amount of liquid is too low, problems arise when mixing, solidification proceeds relatively quickly and granules are formed. If the proportion of water is too large, the mass remains soft for a relatively long time, in cases the setting process takes place only after a few days. This is disadvantageous for the practice of the method.
Amount of solid waste, .e. application 50 ma.ch. or less, does not matter for carrying out the method. Solid waste materials are bound in a hardening mass yi to cover it in such a way that they are almost ok.
ten
15
x 20
476996
stations consisting of sample 3 (tabl-f ca) with water to obtain a zheheobraznogo consistency. After the test specimen has hardened, it is washed with a 10-fold amount of water under continuous circulation of water.
From the data of the experiment with a duration of 6 weeks, it can be seen that the harmful substances of the spent gas-cleaning mass in the eluate are practically not detected.
There is considerable difficulty in the storage at landfills of this waste without its disposal, since the gas-cleaning mass has more than 20% water-soluble components, for example, a few percent of the rohanide (.
By the proposed method, the gas-cleaning mass can be stored anywhere without additional measures.
The drill cores of their forming monolithic block showed that the compressive strength averaged 120 kg / cm 5, water permeability - K ZxHG9m / s. With such extremely low water permeability, the danger of contamination of groundwater is not threatened.
The proposed method differs from the known one in that solid waste is additionally added to the hardening mixture, which is bound to a solid monolith with hardened ash. Stability is controlled only by choosing the ratio of the components, i.e. amounts of ash, waste and water. The materials used are not
25
thirty
35
are protected by a protective sheath which does not have any specific op.

权利要求:
Claims (1)
[1]
permeable to groundwater. Thus, the solid waste is enclosed harmlessly in capsules and thus harmlessly stored. If more than 50 May is used, h, solid waste, then the sufficient surrounding of the waste with the casing is no longer ensured, in particular there is a danger, than solid waste located near the edge of the dump is washed out, since the casing is not sufficient for reliable and wall The capsules are not thick enough. By this prohibit the use of more than 50 ma.ch. solid outgoing properties to ensure the required stability of the hardened mass. Invention Formula
A method of harmless storage of waste, including mixing brown coal ash - waste power plants with water to obtain a slurry fluid mass, storing it in a heap and maintaining until complete curing, characterized in that, in order to increase the efficiency of the method by disposing mixing the ash of brown coal waste power plants with water to obtain a slushy fluid mass, storing it in the dump and keeping until complete curing, characterized in This is to increase the cost-effectiveness of the method by utilizing the dodes.
Example 3. To test the pre-solid solid toxic process, the tests are made, before mixing with water to the produced sample of 1.8 t in weight, brown coal is added to the spent gas purification mass and ash brown coal electron catalyst based on iron oxide - waste petrochemical industry5
d
defined properties to ensure the required stability of the hardened mass. Invention Formula
A method of harmless storage of waste, including mixing brown coal ash — waste power plants with water to obtain a slushy fluid mass, storing it in a dump and keeping it completely cured, characterized in that, in order to increase the efficiency of the method by disposing of solid solid toxic waste before mixing with water, brown coal is added to the aeol of brown coal.
ferrous oxide based catalyst - waste of the petrochemical industry or spent crushed gas cleaning mass - waste of coke plants with the ratio of brown coal ash and water in ma.ch. (5-50):
ten
20
50
50
72 Loose, not stirred
80 Pasty
: 100: (20-40), and storage of the resulting mass is carried out by distributing it along the bottom and side surfaces of the heap.
Hardened (hard)
Hardening
nach,
Solid

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同族专利:

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公开号 | 公开日

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DE3039660A1|1982-04-29|

引用文献:

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DE2652107C3|1975-11-20|1979-03-29|Societe De Prayon, Prayon, Foret |Process for stabilizing and solidifying residues containing metal compounds|

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DE2638224C2|1976-08-25|1978-10-26|Basf Ag, 6700 Ludwigshafen|Process for the transfer of viscous, reactive chlorine and sulfur-containing production residues into landfillable products|

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DE2925882C2|1979-06-27|1986-10-23|Günther Dr. 4154 Tönisvorst Heide|Process for processing lignite ash containing water-soluble sulphates for landfill|DE3506550A1|1985-02-25|1986-08-28|Heinrich 4250 Bottrop Becker|Method and apparatus for the non-harmful dumping of substances which pose a threat to the environment by binding them with power station ash|

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DE3634650A1|1986-10-10|1988-05-19|Hoelter Gmbh|METHOD FOR DISPOSAL OF POLLUTANT-laden SUBSTANCES AND USE OF THE PRODUCT PRODUCED THEREOF|

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DE3722995C2|1987-07-11|1990-02-08|Gfr Gesellschaft Fuer Die Aufbereitung Und Verwertung Von Reststoffen Mbh, 8715 Iphofen, De|

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DE3732329A1|1987-09-25|1989-04-13|Hoelter Heinz|Process for treating heavy-metal-containing waste waters|

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DE19538839A1|1995-10-19|1997-04-24|Urt Umwelttechnik Gmbh|Immobilising heavy metals, especially radioactive heavy metals|

法律状态:

优先权:

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DE19803039660|DE3039660A1|1980-10-21|1980-10-21|METHOD FOR THE DAMAGED DEPOSIT OF THICKEN ACID ON LAND|

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